《Diiminepyridine-Supported Phosphorus(I) and Phosphorus(III) Complexes: Synthesis, Characterization, and Electrochemistry》 was written by Gray, Paul A.; Braun, Jason D.; Rahimi, Naser; Herbert, David E.. Recommanded Product: 626-05-1 And the article was included in European Journal of Inorganic Chemistry in 2020. The article conveys some information:
Diiminepyridines (DIP) are popular redox noninnocent ligands with widespread application in late, 1st-row transition metal mediated catalysis and coordination chem. Here, the authors report the isolation and characterization of a pair of P coordination complexes in the +1 and +3 oxidation states supported by the same ligand framework bearing sterically imposing and electron-releasing tBu substituents on the imine carbons of the DIP backbone. Electrochem. anal. demonstrates that the DIP scaffold can retain its ability to serve as an electron reservoir when coordinated to a reduced pnicogen center, with a reversible reduction observed for the PI complex. The experimental process involved the reaction of 2,6-Dibromopyridine(cas: 626-05-1Recommanded Product: 626-05-1)
2,6-Dibromopyridine(cas: 626-05-1) belongs to pyridine. Pyridine derivatives lend themselves to many roles in the spirited field of supramolecular chemistry – whether as the ligand backbone of metal-organic polymers or presiding over the key electronic stations of nanodevices. In biochemistry, pyridine-containing cofactors are necessary nutrients on which our lives depend. Recommanded Product: 626-05-1