Guo, Zhewen; Zhao, Jun; Liu, Yuhang; Li, Guangfeng; Wang, Heng; Hou, Yali; Zhang, Mingming; Li, Xiaopeng; Yan, Xuzhou published an article in 2021. The article was titled 《Conformational effect on fluorescence emission of tetraphenylethylene-based metallacycles》, and you may find the article in Chinese Chemical Letters.Application In Synthesis of Pyridin-3-ylboronic acid The information in the text is summarized as follows:
Herein, the authors designed and constructed two metallacycles, 1 and 2, to illustrate the conformational effect of isomeric AIE fluorophores on the platform of supramol. coordination complexes (SCCs). Specifically, the dangling Ph rings in TPE units of the metallacycle 1 align completely outside the main cyclic structure, while in the metallacycle 2, these Ph rings align half inside and half outside. The exptl. results showed that two metallacycles exhibited different behaviors in terms of AIE fluorescence and chem. sensing, which could be attributed to the subtle structural difference of the TPE units. This work represents the unification of topics such as self-assembly, AIE, and chem. sensing, and further promotes the understanding for the structure-property relationship of isomeric AIE fluorophores.Pyridin-3-ylboronic acid(cas: 1692-25-7Application In Synthesis of Pyridin-3-ylboronic acid) was used in this study.
Pyridin-3-ylboronic acid(cas: 1692-25-7) belongs to pyridine. Pyridine derivatives lend themselves to many roles in the spirited field of supramolecular chemistry – whether as the ligand backbone of metal-organic polymers or presiding over the key electronic stations of nanodevices. In biochemistry, pyridine-containing cofactors are necessary nutrients on which our lives depend. Application In Synthesis of Pyridin-3-ylboronic acid