Iridium-catalyzed cleavage of C-O bonds using alcohols as reducing reagents was written by Hibe, Yuta;Ebe, Yusuke;Nishimura, Takahiro;Yorimitsu, Hideki. And the article was included in Chemistry Letters in 2017.Product Details of 4373-61-9 This article mentions the following:
A cationic iridium/binap catalyst-enabled reductive cleavage of C(sp2)-O bonds of aromatic compounds having nitrogen-based directing groups, such as 2-(2-butoxyphenyl)pyridine, 2-(2-methoxyphenyl)quinoline, 2-(2-methoxyphenyl)-1,3-benzothiazole, etc. was carried out in the presence of 2-propanol as reducing reagent. In the experiment, the researchers used many compounds, for example, 2-(m-Tolyl)pyridine (cas: 4373-61-9Product Details of 4373-61-9).
2-(m-Tolyl)pyridine (cas: 4373-61-9) belongs to pyridine derivatives. Pyridine is diamagnetic and has a diamagnetic susceptibility of −48.7 × 10−6 cm3·mol−1.The molecular electric dipole moment is 2.2 debyes. The standard enthalpy of formation is 100.2 kJ·mol−1 in the liquid phase and 140.4 kJ·mol−1 in the gas phase. Reduced pyridines, namely tetrahydropyridines, dihydropyridines and piperidines, are found in numerous natural and synthetic compounds. The synthesis and reactivity of these compounds have often been driven by the fact many of these compounds have interesting and unique pharmacological properties. Product Details of 4373-61-9