Push-Pull Stabilization of Parent Monochlorosilylenes was written by Hickox, Hunter P.;Wang, Yuzhong;Xie, Yaoming;Wei, Pingrong;Schaefer, Henry F.;Robinson, Gregory H.. And the article was included in Journal of the American Chemical Society in 2016.Recommanded Product: 628-13-7 This article mentions the following:
While reaction of carbene-stabilized disilicon LSi:SiL (L: = C{N(2,6-iPr2C6H3)CH}2) (8) with HCl·NC5H5 results in carbene-stabilized Si2Cl2 (2) and substituted 1H-imidazole (9), combination of the corresponding Fe(CO)4-modified disilicon carbene complex LSi:Si[Fe(CO)4]L (6) with pyridine hydrochloride gives a species containing two push-pull-stabilized parent monochlorosilylenes that are bridged by an Fe(CO)3 unit (7). The nature of 7 was further elucidated by spectroscopic, crystallog., and computational methods. Spectroscopic data suggest that 7 exists as two diastereoisomers. In the experiment, the researchers used many compounds, for example, Pyridinehydrochloride (cas: 628-13-7Recommanded Product: 628-13-7).
Pyridinehydrochloride (cas: 628-13-7) belongs to pyridine derivatives. Pyridine’s the lone pair does not contribute to the aromatic system but importantly influences the chemical properties of pyridine, as it easily supports bond formation via an electrophilic attack. One of the examples of pyridines is the well-known alkaloid lithoprimidine, which is an A3 adenosine receptor antagonist and N,N-dimethylaminopyridine (DMAP) analog, commonly used in organic synthesis.Recommanded Product: 628-13-7