Application In Synthesis of 2-(Bromomethyl)pyridine hydrobromideIn 2022 ,《Group 12 metal complexes of mixed thia/aza and thia/oxa/aza macrocyclic ligands》 was published in Polyhedron. The article was written by Hodorogea, Ana Maria; Silvestru, Anca; Lippolis, Vito; Pop, Alexandra. The article contains the following contents:
The coordination behavior of the macrocyclic ligands N-(2-pyridylmethyl)-[12]aneNS2O (L1) and N-(2-pyridylmethyl)-[12]aneNS3 (L2) ([12]aneNS2O = 1-aza-4,10-dithia-7-oxacyclododecane, [12]aneNS3 = 1-aza-4,7,10-trithia-cyclododecane) was studied in complexation reactions with ZnCl2, CdI2 and HgCl2. The NMR and mass spectra suggest the formation of the ionic species [LMX]2[MX4] [M = Zn, X = Cl, L = L1 (1), L2 (2); M = Cd, X = I, L = L1 (3), L2 (4); M = Hg, X = Cl, L = L1 (5), L2 (6)]. The x-ray diffraction studies confirmed the formation of the new species 3-6, with [LMX]+ cations and [MX4]2- anions, while for the zinc(II) complex 1 the determined structure corresponds to the hydrolysis product of formula [L1Zn]2[ZnCl3]2[Zn2Cl6]·2H2O (1h), with [L1Zn(H2O)]2+ cations and [ZnCl3(H2O)]- and [Zn2Cl6]2- anions. In all complexes the metal ion is hexacoordinated in cations, while in anions the metal is tetrahedrally surrounded by halido ligands. In addition to this study using 2-(Bromomethyl)pyridine hydrobromide, there are many other studies that have used 2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8Application In Synthesis of 2-(Bromomethyl)pyridine hydrobromide) was used in this study.
2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8) belongs to pyridine. Pyridines, quinolines, and isoquinolines have found a function in almost all aspects of organic chemistry. Pyridine has found use as a solvent, base, ligand, functional group, and molecular scaffold. As structural elements, these moieties are potent electron-deficient groups, metal-directing functionalities, fluorophores, and medicinally important pharmacophores. Application In Synthesis of 2-(Bromomethyl)pyridine hydrobromide