Electrochemical reduction of dodecylpyridinium bromide in aprotic solvents: mechanistic studies was written by Hromadova, Magdalena;Pospisil, Lubomir;Sokolova, Romana;Kolivoska, Viliam. And the article was included in Collection of Czechoslovak Chemical Communications in 2011.Category: pyridine-derivatives This article mentions the following:
Reduction mechanism of 1-dodecylpyridin-1-ium bromide (DPBr) in dimethylsulfoxide was studied on Hg electrode. Based on the classical polarog. methods as well as on the use of a.c. techniques it was shown that DPBr is reduced in a reversible one electron transfer step followed by dimerization of the corresponding radical species. Reduction process is accompanied by the adsorption phenomena even in the non-aqueous solvents. Possible modes of DPBr adsorption were studied by the ex situ scanning tunnelling microscopy (STM) imaging of these mols. on highly oriented pyrolytic graphite. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Category: pyridine-derivatives).
1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. Pyridine’s the lone pair does not contribute to the aromatic system but importantly influences the chemical properties of pyridine, as it easily supports bond formation via an electrophilic attack. Halopyridines are particularly attractive synthetic building blocks in a variety of cross-coupling methods, including the Suzuki-Miyaura cross-coupling reaction.Category: pyridine-derivatives