《Radical Stabilization of a Tripyridinium-Triazine Molecule Enables Reversible Storage of Multiple Electrons》 was written by Huang, Jinghua; Hu, Shuzhi; Yuan, Xianzhi; Xiang, Zhipeng; Huang, Mingbao; Wan, Kai; Piao, Jinhua; Fu, Zhiyong; Liang, Zhenxing. Computed Properties of C6H4N2This research focused ontripyridinium triazine radical stabilization; aqueous; multi-electron storage; pyridinium; radical stabilization; triazine. The article conveys some information:
A novel organic mol., 2,4,6-tris[1-(trimethylamonium)propyl-4-pyridiniumyl]-1,3,5-triazine hexachloride, was developed as a reversible six-electron storage electrolyte for use in an aqueous redox flow battery (ARFB). Physicochem. characterization reveals that the mol. evolves from a radical to a biradical and finally to a quinoid structure upon accepting four electrons. Both the diffusion coefficient and the rate constant were sufficiently high to run a flow battery with low concentration and kinetics polarization losses. In a demonstration unit, the assembled flow battery affords a high specific capacity of 33.0 Ah L-1 and a peak power d. of 273 mW cm-2. This work highlights the rational design of electroactive organics that can manipulate multi-electron transfer in a reversible way, which will pave the way to development of energy-dense, manageable and low-cost ARFBs. After reading the article, we found that the author used 4-Cyanopyridine(cas: 100-48-1Computed Properties of C6H4N2)
4-Cyanopyridine(cas: 100-48-1) belongs to pyridine. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Additionally, pyridine-based natural products continue to be discovered and studied for their properties and to understand their biosynthesis.Computed Properties of C6H4N2