Jalba, Angela; Regnier, Noemie; Ollevier, Thierry published the artcile< Enantioselective Aromatic Sulfide Oxidation and Tandem Kinetic Resolution Using Aqueous H2O2 and Chiral Iron-Bis(oxazolinyl)bipyridine Catalysts>, Application In Synthesis of 147409-41-4, the main research area is aromatic sulfoxide sulfone enantioselective preparation; arylsulfide enantioselective oxidation iron chiral ligand catalyst.
An efficient method for the oxidation of aromatic sulfides has been developed by using aqueous H2O2, catalyzed by the in situ generated chiral Fe/6,6′-bis(4-isopropyloxazolin-2-yl)-2,2′-bipyridine (bipybox-iPr) complex. The corresponding sulfoxides were obtained with high enantioselectivities (up to 98.5:1.5 er) and in good yields (up to 61 %) when the mono-oxidation of the sulfides was performed in combination with the kinetic resolution of the sulfoxide into the sulfone.
European Journal of Organic Chemistry published new progress about Amino alcohols, chiral Role: RCT (Reactant), RACT (Reactant or Reagent). 147409-41-4 belongs to class pyridine-derivatives, and the molecular formula is C22H26N4O2, Application In Synthesis of 147409-41-4.