Kang, Yan-Shang; Zhang, Ping; Li, Min-Yan; Chen, You-Ke; Xu, Hua-Jin; Zhao, Jing; Sun, Wei-Yin; Yu, Jin-Quan; Lu, Yi published the artcile< Ligand-Promoted RhIII-Catalyzed Thiolation of Benzamides with a Broad Disulfide Scope>, Reference of 2127-03-9, the main research area is benzamide pentafluorophenyl disulfide rhodium amino acid regioselective thiolation catalyst; arylthio pentafluorophenyl benzamide preparation; amino acids; directing groups; disulfides; rhodium; thiolation.
A ligand-promoted RhIII-catalyzed C(sp2)-H activation/thiolation of benzamides has been developed. Using bidentate mono-N-protected amino acid ligands led to the first example of RhIII-catalyzed aryl thiolation reactions directed by weakly coordinating directing amide groups. The reaction tolerates a broad range of amides and disulfide reagents.
Angewandte Chemie, International Edition published new progress about Amino acids Role: CAT (Catalyst Use), USES (Uses). 2127-03-9 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2S2, Reference of 2127-03-9.