Application In Synthesis of Bis(pyridin-2-ylmethyl)amineIn 2022 ,《Synthesis, characterization, structural, redox and electrocatalytic proton reduction properties of cobalt polypyridyl complexes》 appeared in Inorganica Chimica Acta. The author of the article were Karumban, Kalai Selvan; Muley, Arabinda; Giri, Bishnubasu; Kumbhakar, Sadananda; Kella, Tatinaidu; Shee, Debaprasad; Maji, Somnath. The article conveys some information:
A monoanionic amido pentadentate ligand bpaqH (2-(bis(pyridin-2-ylmethyl)amino)-N-(quinolin-8-yl)acetamide) and its corresponding cobalt(III) chloro complex [Co(bpaq)Cl]Cl: 1 and aqua derivative [Co(bpaq)(OH2)](ClO4)2: 2 were successfully synthesized and fully characterized by different anal. and spectroscopic techniques such as FT-IR, 1H NMR, UV-vis spectroscopy, ESI mass spectra. The structures of 1 and 2 have been determined by the single-crystal x-ray diffraction. Spectral and redox properties were investigated along with free ligand under electrochem. conditions. Both complexes performed proton reduction activity under soluble, diffusion-limited conditions in acetonitrile with acetic acid as an external proton source with overpotentials of 0.412 V for 1 and 0.394 V for 2. The stability of the catalysts was inspected by the time-dependent UV-vis spectroscopy; 1 and 2 were highly stable in the absence and presence of acetic acid. There was no significant spectral change before and after the controlled potential electrolysis suggesting no change in mol. integrity during electrocatalysis. In the experimental materials used by the author, we found Bis(pyridin-2-ylmethyl)amine(cas: 1539-42-0Application In Synthesis of Bis(pyridin-2-ylmethyl)amine)
Bis(pyridin-2-ylmethyl)amine(cas: 1539-42-0) is a secondary amine with two picolyl substituents. The compound is a tridentate ligand in coordination chemistry and commonly used to produce Zn-based chemosensors/probes, such as Zinpry.Application In Synthesis of Bis(pyridin-2-ylmethyl)amine