Kizu, Tomohito; Uraguchi, Daisuke; Ooi, Takashi published the artcile< Independence from the Sequence of Single-Electron Transfer of Photoredox Process in Redox-Neutral Asymmetric Bond-Forming Reaction>, Name: Ir(p-F-ppy)3, the main research area is enantioselective coupling arylaminomethane methanesulfonylaldimine iridium photosensitizer.
A catalytic cycle initiated by the oxidative quenching of the excited photosensitizer (Ir*(ppy)3) is established for the enantioselective coupling between (N-arylamino)methanes and (N-methanesulfonyl)aldimines catalyzed by Ir-based photosensitizer and a chiral (arylamino)phosphonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate under visible light irradiation This achievement clearly demonstrates the insensitivity of this redox-neutral asym. reaction to the sequence of the key redox events involved in the synergistic catalysis.
Journal of Organic Chemistry published new progress about Aldimines Role: RCT (Reactant), RACT (Reactant or Reagent). 370878-69-6 belongs to class pyridine-derivatives, and the molecular formula is C33H21F3IrN3, Name: Ir(p-F-ppy)3.