Kunfi, Attila; Jablonkai, Istvan; Gazdag, Tamas; Mayer, Peter J.; Kalapos, Peter Pal; Nemeth, Krisztina; Holczbauer, Tamas; London, Gabor published their research in RSC Advances in 2021. The article was titled 《A photoresponsive palladium complex of an azopyridyl-triazole ligand: light-controlled solubility drives catalytic activity in the Suzuki coupling reaction》.Product Details of 13534-97-9 The article contains the following contents:
Herein, the design and synthesis of a click-derived Pd-complex merged with a photoswitchable azobenzene unit is presented. While in the trans-form of the switch the complex showed limited solubility, the photogenerated cis-form rendered the mol. soluble in polar solvents. This light-controllable solubility was exploited to affect the catalytic activity in the Suzuki coupling reaction. The effect of the substrate and catalyst concentration and light intensity on the proceeding and outcome of the reaction was studied. Dehalogenation of the aryl iodide starting material was found to be a major side reaction; however, its occurrence was dependent on the applied light intensity. The experimental process involved the reaction of 6-Bromopyridin-3-amine(cas: 13534-97-9Product Details of 13534-97-9)
6-Bromopyridin-3-amine(cas: 13534-97-9) belongs to anime. Left-handed and right-handed forms (mirror-image configurations, known as optical isomers or enantiomers) are possible when all the substituents on the central nitrogen atom are different (i.e., the nitrogen is chiral). With amines, there is extremely rapid inversion in which the two configurations are interconverted.Product Details of 13534-97-9