Kuzuya, Masayuki; Noguchi, Akihiro; Mano, Eiichi; Okuda, Takachiyo published the artcile< The structure-reactivity-chemoselectivity relationship on the reactions of 1-unsubstituted tautomeric 2-pyridones with benzyne>, Product Details of C5H4ClNO, the main research area is tautomerism pyridone reaction benzyne.
The effect of tautomerism of 2-pyridones on the products obtained in reaction with benzyne was studied. Both Diels-Alder and Michael-type adducts were formed. The Diels-Alder reactivities were correlated with HOMO energy levels of the 2-pyridone form; the yields of the Michael-type adducts were associated with the tautomeric equilibrium Substituent effects on the tautomerism were discussed.
Bulletin of the Chemical Society of Japan published new progress about CNDO/2 (molecular orbital method). 73018-09-4 belongs to class pyridine-derivatives, and the molecular formula is C5H4ClNO, Product Details of C5H4ClNO.