Li, Chaojie; Wei, Zhangwen; Pan, Mei; Deng, Haiying; Jiang, Jijun; Su, Chengyong published the artcile< Structural tuning of coordination polymers by 4-connecting metal node and secondary building process>, Synthetic Route of 3731-53-1, the main research area is transition metal pyridylmethylnaphthalenediimide coordination polymer preparation crystal structure.
Five transition metal coordination polymers, {[Cu(4-pmntd)2(NO3)2]•2CHCl3}n (1), {[Cu(4-pmntd)2(NO3)2]·3C7H8}n (2), {[Cu(4-pmntd)2(CF3SO3)(H2O)]·CF3SO3·H2O·MeOH}n (3), [Cd(4-pmntd)2]n·nSiF6·x(MeOH)·y(CHCl3) (4), and [Zn(4-pmntd)2(CF3SO3)2]n·x(solvent) (5), were obtained from a ditopic ligand, N,N’-bis(4-pyridylmethyl)naphthalene diimide (4-pmntd). Either sql- or dia- structures are generated from four connecting coordination nodes of the metal centers. While delicate interpenetration and structural tuning in these complexes is achieved by the different conformations and spatially extending geometries adopted by the ligand and secondary building process induced by pillar-like anions.
Chinese Chemical Letters published new progress about Coordination polymers Role: PRP (Properties), SPN (Synthetic Preparation), PREP (Preparation). 3731-53-1 belongs to class pyridine-derivatives, and the molecular formula is C6H8N2, Synthetic Route of 3731-53-1.