Liu, Meng; Mu, Yan-Fei; Yao, Shuang; Guo, Song; Guo, Xiang-Wei; Zhang, Zhi-Ming; Lu, Tong-Bu published the artcile< Photosensitizing single-site metal-organic framework enabling visible-light-driven CO2 reduction for syngas production>, Recommanded Product: 2,2′-Bipyridine, the main research area is photosensitizing MOF carbon reduction syngas.
Photocatalytic CO2 reduction into syngas (CO and H2) is one of sustainable strategies for recycling CO2 into value-added products. Herein, a simple and effective two-step self-assembly process was developed to functionalize phosphorescent metal-organic framework (MOF) with single site catalyst. The resulting (Co/Ru)n-UiO-67(bpydc) supplied mol. platform to enable fast multielectron injection from photosensitizers (PSs) to Co-catalyst, leading to the first MOF-based composite photocatalyst for efficient syngas production with a yield of 13,600μmol·g-1 (H2 : CO = 2 : 1) in 16 h, 29.2-fold higher than that of its homogeneous counterpart. The H2/CO ratios can be well controlled by carefully adjusting the molar ratio of PS/catalyst in the MOF platform and the water content in the photocatalytic system. This work provides a prospective strategy for recycling CO2 into H2-rich syngas by merging PSs and single-site catalysts into a MOF platform.
Applied Catalysis, B: Environmental published new progress about Photocatalysts. 366-18-7 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2, Recommanded Product: 2,2′-Bipyridine.