Robust perfluorinated porous organic networks: Succinct synthetic strategy and application in chlorofluorocarbons adsorption was written by Luo, Yali;Yang, Zhenzhen;Suo, Xian;Chen, Hao;Wang, Tao;Wang, Ziqian;Liu, Yunfei;Lyu, Yinong;Popovs, Ilja;Dai, Sheng. And the article was included in Nano Research in 2021.Computed Properties of C5F5N The following contents are mentioned in the article:
Fluorinated porous organic networks (F-PONs) have demonstrated unique properties and applications, but approaches capable of affording F-PONs with high fluorine content and robust nanoporous architecture under metal-free and easy handling conditions are still rarely reported. Herein, using polydivinylbenzene (PDVB) as an easily available precursor, a novel and straightforward approach was developed to afford F-PONs via a dehydrative Friedel-Crafts reaction using perfluorinated benzylic alcs. as the crosslinking agent promoted by Bransted acid (trifluoromethanesulfonic acid). The afforded material (F-PDVB) featured high fluorine content (22 at.%), large surface area (771 m2·g-1), and good chem./thermal stability, rendering them as promising candidates for the adsorption of CO2, hydrocarbons, fluorocarbons, and chlorofluorocarbons, with weight capacities up to 520 weight% being achieved. This simple methodol. can be extended to fabricate fluorinated hyper-crosslinked polymers (F-HCPs) from rigid aromatic monomers. The progress made in this work will open new opportunities to further expand the involvement of fluorinated materials in large scale applications. This study involved multiple reactions and reactants, such as 2,3,4,5,6-Perfluoropyridine (cas: 700-16-3Computed Properties of C5F5N).
2,3,4,5,6-Perfluoropyridine (cas: 700-16-3) belongs to pyridine derivatives. Pyridine’s the lone pair does not contribute to the aromatic system but importantly influences the chemical properties of pyridine, as it easily supports bond formation via an electrophilic attack. Several pyridine derivatives play important roles in biological systems. While its biosynthesis is not fully understood, nicotinic acid (vitamin B3) occurs in some bacteria, fungi, and mammals.Computed Properties of C5F5N