Lv, Cong; Liu, Dan; Muschin, Tegshi; Bai, Chaolumen; Bao, Agula; Bao, Yong-Sheng published an article in 2022, the title of the article was From amides to urea derivatives or carbamates with chemospecific C-C bond cleavage at room temperature.HPLC of Formula: 156267-13-9 And the article contains the following content:
Herein, a significant advancement in this area and present a general method for copper-catalyzed chemospecific C-C bond cleavage of amides to synthesize urea derivatives and carbamates at room temperature was reported. A catalytic process via a resonant six-membered N,O-chelated copper cycle and superoxide radical was proposed according to mechanistic and control experiments The combination of chelation assistance and radical oxygenation strategies opened a door for C-C bond cleavage of common substrates which possess multiple reactive sites and was envision that this broadly applicable method will be of great interest in organic synthesis, the pharmaceutical industry and the agrochem. industry. The experimental process involved the reaction of N,3-Dimethylpyridin-2-amine(cas: 156267-13-9).HPLC of Formula: 156267-13-9
The Article related to diaryl acetamide copper catalyst chemoselective bond cleavage, aryl aldehyde preparation, amine pyridinyl diphenylacetamide copper catalyst chemoselective bond cleavage, pyridinyl urea preparation, alc methylpyridinyl diphenylacetamide copper catalyst chemoselective bond cleavage, methylpyridinyl carbamate preparation and other aspects.HPLC of Formula: 156267-13-9