Application of 31251-41-9, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 31251-41-9, Name is 8-Chloro-5,6-dihydro-11H-benzo[5,6]cyclohepta[1,2-b]pyridin-11-one, SMILES is O=C1C2=CC=C(Cl)C=C2CCC3=CC=CN=C31, belongs to pyridine-derivatives compound. In a article, author is Chanerika, Revana, introduce new discover of the category.
Application of new Ru (II) pyridine-based complexes in the partial oxidation of n-octane
Tridentate and bidentate Ru (II) complexes were prepared through reaction of four pyridine-based ligands: pyCH(2)N(R)CH(2)py {R = propyl, tert-butyl, cyclohexyl and phenyl; py = pyridine} with the [(eta(6)-C6H6)Ru(mu-Cl)Cl](2) dimer. Crystal structures of the new terdentate Ru (II) complexes [Ru{pyCH(2)N(R)CH(2)py}C6H6](PF6)(2) (R = C3H7 (1), C (CH3)(3) (2), C6H11 (3) and the bidentate Ru (II) complex [Ru{pyCH(2)N(R)}C6H6]PF6 (R = C6H5 (4)) are reported. It was found that complexes 1, 2, 3 and 4 crystallised as mono-metallic species, with a piano stool geometry around each Ru centre. All complexes were active in the selective oxidation of n-octane using t-BuOOH and H2O2 as oxidants. Complexes 2 and 4 reached a product yield of 12% with t-BuOOH as oxidant, however, superior yields (23-32%) were achieved using H2O2 over all systems. The selectivity was predominantly towards alcohols (particularly 2-octanol) over all complexes using t-BuOOH and H2O2 after reduction of the formed alkylhydroperoxides in solution by PPh3. High TONs of up to 2400 were achieved over the Ru/H2O2 systems.
Application of 31251-41-9, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 31251-41-9 is helpful to your research.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem