Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Mori, Daiki, once mentioned the application of 13362-78-2, Name is (E)-1,2-Di(pyridin-4-yl)ethene, molecular formula is C12H10N2, molecular weight is 182.22, MDL number is MFCD00006448, category is pyridine-derivatives. Now introduce a scientific discovery about this category, Computed Properties of C12H10N2.
meso-Diketopyripentaphyrin and Diketopyrihexaphyrin as Macrocyclic Tripyrrinone Ligands for Ni-II Ions
We report expanded porphyrins with pyridine rings and two neighboring carbonyl groups, which allow Ni-II ions to coordinate to the tripyrrinone-type NNNO coordination structure with Ni-O bonds. The selectivity of tripyrrinone is superior to other pyrrolic or pyridinic cavities of expanded porphyrins. Introduction of alpha-carbonyl pyridine next to the tripyrrolic conjugated structure is a powerful strategy for regioselective metalation of flexible expanded porphyrinoids.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem