Qiu, Xu; Yang, Xiaoxue; Zhang, Yiqun; Song, Song; Jiao, Ning published the artcile< Efficient and practical synthesis of unsymmetrical disulfides via base-catalyzed aerobic oxidative dehydrogenative coupling of thiols>, Recommanded Product: 1,2-Di(pyridin-2-yl)disulfane, the main research area is disulfide green preparation; thiol oxidative dehydrogenative coupling base catalyst.
An efficient M2CO3-catalyzed (M = K or Cs) aerobic cross dehydrogenative coupling reaction of thiols to afford unsym. disulfides RSSR1 [R = 4-MeC6H4, 2-pyridyl, 4-ClC6H4CH2, etc.; R1 = t-Bu, Bn, 2-naphthyl, etc.] was described. The high atom-economy, easy accessibility of catalyst, O2 as the ideal green oxidant, mild reaction conditions and broad substrate scope demonstrated that the present methodol. as a green, attractive and practical approach to disulfides.
Organic Chemistry Frontiers published new progress about Disulfides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 2127-03-9 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2S2, Recommanded Product: 1,2-Di(pyridin-2-yl)disulfane.