Rathnayake, Manjula D.; Weaver, Jimmie D. III published their research in Organic Letters in 2021. The article was titled 《Coupling Photocatalysis and Substitution Chemistry to Expand and Normalize Redox-Active Halides》.Product Details of 100-48-1 The article contains the following contents:
Photocatalysis can generate radicals in a controlled fashion and has become an important synthetic strategy. However, limitations due to the reducibility of alkyl halides prevent their broader implementation. Herein authors explore the use of nucleophiles that can substitute the halide and serve as an electron capture motif that normalize the variable redox potentials across substrates. When used with photocatalysis, bench-stable, com. available collidinium salts prove to be excellent radical precursors with a broad scope. The results came from multiple reactions, including the reaction of 4-Cyanopyridine(cas: 100-48-1Product Details of 100-48-1)
4-Cyanopyridine(cas: 100-48-1) belongs to pyridine. Pyridines are often used as catalysts or reagents; particular notice has been paid recently to how pyridine coordinates to metal centers enabling a wide range of valuable reactions. Product Details of 100-48-1