Alkylation of pyridine in free radical chain reactions utilizing alkylmercurials was written by Russell, Glen A.;Guo, Deliang;Khanna, Rajive K.. And the article was included in Journal of Organic Chemistry in 1985.HPLC of Formula: 27876-24-0 This article mentions the following:
Pyridines or N,N,N‘,N‘-tetramethyl-p-phenylenediamine will undergo a photostimulated free radical chain reaction with alkylmercury halides or carboxylates yielding ring alkylated substitution products. Alkene mercuration products can be used without isolation for the alkylation reaction. In the experiment, the researchers used many compounds, for example, 4-Hexylpyridine (cas: 27876-24-0HPLC of Formula: 27876-24-0).
4-Hexylpyridine (cas: 27876-24-0) belongs to pyridine derivatives. Pyridine has a dipole moment and a weaker resonant stabilization than benzene (resonance energy 117 kJ·mol−1 in pyridine vs. 150 kJ·mol−1 in benzene). Pyridine derivatives are also useful as small-molecule α-helix mimetics that inhibit protein-protein interactions, as well as functionally selective GABA ligands.HPLC of Formula: 27876-24-0