Saidalimu, Ibrayim; Liang, Yumeng; Niina, Kiyoteru; Tanagawa, Kazuhiro; Saito, Norimichi; Shibata, Norio published the artcile< Synthesis of aryl and heteroaryl tetrafluoro-λ6-sulfanyl chlorides from diaryl disulfides using trichloroisocyanuric acid and potassium fluoride>, Synthetic Route of 2127-03-9, the main research area is aryl heteroaryl tetrafluoro sulfanyl chloride preparation; diaryl disulfide trichloroisocyanuric acid potassium fluoride oxidative chlorotetrafluorination.
A catalyst-free method for the synthesis of aryl and heteroaryl tetrafluoro-λ6-sulfanyl chlorides (Ar-SF4Cl) by using trichloroisocyanuric acid and potassium fluoride in acetonitrile was presented. The method has wide substrate generality and proceeded well with high yields even in the absence of acid catalysts. The preparation of meta- and para-SF4Cl-substituted pyridines using TCCA was achieved for the first time.
Organic Chemistry Frontiers published new progress about Aromatic compounds, disulfides Role: RCT (Reactant), RACT (Reactant or Reagent). 2127-03-9 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2S2, Synthetic Route of 2127-03-9.