On February 28, 1985, Sakamoto, Takao; Kaneda, Sohichi; Nishimura, Sumiko; Yamanaka, Hiroshi published an article.Computed Properties of 97483-79-9 The title of the article was Site-selectivity in the cyanation of 3-substituted pyridine 1-oxides with trimethylsilanecarbonitrile. And the article contained the following:
Treatment of pyridine 1-oxides I (R = Br, Cl, F, OMe, NMe2, Me, Et, Ph, CONEt2, CO2Et, cyano) with Me3SiCN gave 2- and 6-cyanopyridines II and III. The II – III ratio was strongly influenced by R, with II being the only product when R = F, OMe, NMe2. Nitropyridine 1-oxides underwent deoxygenation but not cyanation with Me3SiCN. The experimental process involved the reaction of Ethyl 6-cyanopicolinate(cas: 97483-79-9).Computed Properties of 97483-79-9
The Article related to pyridine oxide trimethylsilyl cyanide cyanation, cyanopyridine, deoxygenation pyridine oxide trimethylsilyl cyanide, Heterocyclic Compounds (One Hetero Atom): Pyridines and other aspects.Computed Properties of 97483-79-9