Sakla, Rahul; Amilan Jose, D. published an article in 2021. The article was titled 《New fluorinated manganese carbonyl complexes for light controlled carbon monoxide (CO) release and the use of bench-top 19F-NMR spectroscopy》, and you may find the article in Inorganica Chimica Acta.HPLC of Formula: 1539-42-0 The information in the text is summarized as follows:
CO is used as an essential therapeutic agent. Control delivery and tracking of CO is the important concern for using in therapeutics. The authors report fluorinated Mn(I) tricarbonyl complexes PF-DPA perfluorobenzyl-dipicolinylamine, Mn and CF-DPA·Mn (CF-DPA = trifluoromethylbenzyl-dipicolinylamine) as a new photoCORMs for photo-controlled CO release. For the 1st time, the bench-top 19F-NMR on-off signal was used to monitor light-controlled CO release along with other traditional methods. 19F-NMR signal was initially on which attenuates on irradiating with blue light due to conversion of Mn(I) to Mn(II). CO release behavior of new complexes was also supported by Myoglobin assay, time-dependent IR study and UV-visible experiments Fluorinated Mn carbonyl complexes with 19F-NMR open up vast opportunities for researchers to develop a fast and reliable technique for tracking CO release. In the part of experimental materials, we found many familiar compounds, such as Bis(pyridin-2-ylmethyl)amine(cas: 1539-42-0HPLC of Formula: 1539-42-0)
Bis(pyridin-2-ylmethyl)amine(cas: 1539-42-0) is a secondary amine with two picolyl substituents. As a tridentate ligand this compound provides three nitrogen donors that affords good selectivity for Zn2+ over biologically relevant metals such as Na+, K+, Mg2+ and Ca2+, and leaves coordination sites free for anion binding. HPLC of Formula: 1539-42-0