Sano, Tomoharu published the artcileSynthesis of N-(1-Nitropyren-6-yl and 8-yl)-2′-deoxyribonucleosides, HPLC of Formula: 107263-95-6, the publication is Chemical Research in Toxicology (1995), 8(5), 699-702, database is CAplus and MEDLINE.
A new type of 1-nitropyrene-DNA adduct via addition-elimination reaction was synthesized. Treatment of fluorinated 1-nitropyrene with 3′- and 5′-O-protected 2′-deoxyribonucleoside in DMSO at 140 °C afforded N-(1-nitropyren-6-yl or 8-yl)-2′-deoxyribonucleoside, I (R = H, R1 = NO2; R =NO2, R1 = H). These DNA adducts resulted from addition of the exocyclic amino group of deoxynucleosides to the fluorinated carbon of the fluoro-1-nitropyrene following elimination of fluoride anion. This is the first report that describes the 1-nitropyrene-DNA adducts in which aromatic ring moiety of 1-nitropyrene is covalently linked to the exocyclic amino group of the deoxyribonucleoside. From our findings, we suggest that the addition-elimination reaction may be responsible for the formation mechanism of the putative 1-nitropyrene-DNA adducts in vivo.
Chemical Research in Toxicology published new progress about 107263-95-6. 107263-95-6 belongs to pyridine-derivatives, auxiliary class Fluorination reagent, name is 1-Fluoropyridiniumtriflate, and the molecular formula is C6H5F4NO3S, HPLC of Formula: 107263-95-6.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem