In 2022,Schiltz, Pauline; Casaretto, Nicolas; Auffrant, Audrey; Gosmini, Corinne published an article in Chemistry – A European Journal. The title of the article was 《Cobalt Complexes Supported by Phosphinoquinoline Ligands for the Catalyzed Hydrosilylation of Carbonyl Compounds》.Related Products of 1122-54-9 The author mentioned the following in the article:
Alkoxysilanes ArCHMeOSiHPh2 were prepared by hydrosilylation of acetophenones ArCOMe with SiH2Ph2 catalyzed by cobalt(II) 8-phosphinoquinoline (8-R2Pquin, L; R = iPr, Ph) complexes [(8-R2Pquin)CoBr2] and [(8-R2Pquin)2CoBr][PF6]. P,N phosphinoquinoline based ligands differing by the nature of the phosphorus substituent (iPr, Ph) were employed to synthesize a series of cobalt(II) complexes ([LCoBr2], [L2CoBr](PF6) and [L’2CoBr](PF6)). The complex [(8-Ph2Pquin)2CoBr][PF6] was obtained in high yield and characterized among others by X-ray anal. and elemental anal. Complex [(8-iPr2Pquin)2CoBr][PF6] showed a very good catalytic activity for the hydrosilylation of various ketones. The catalysis proceeds at a low catalytic loading (1 mol %) with only 1 equiv of Ph2SiH2 in mild conditions and was efficient with aliphatic or aromatic ketones giving moderate to excellent yields of the corresponding silylated ether. In addition to this study using 4-Acetylpyridine, there are many other studies that have used 4-Acetylpyridine(cas: 1122-54-9Related Products of 1122-54-9) was used in this study.
4-Acetylpyridine(cas: 1122-54-9) belongs to pyridine. Pyridine derivatives lend themselves to many roles in the spirited field of supramolecular chemistry – whether as the ligand backbone of metal-organic polymers or presiding over the key electronic stations of nanodevices. In biochemistry, pyridine-containing cofactors are necessary nutrients on which our lives depend. Related Products of 1122-54-9