Schwarze, Benedikt; Sobottka, Sebastian; Schiewe, Robert; Sarkar, Biprajit; Hey-Hawkins, Evamarie published the artcile< Spectroscopic and Electronic Properties of Molybdacarborane Complexes with Non-innocently Acting Ligands>, Formula: C10H8N2, the main research area is molybdacarborane containing bipyridine phenanthroline noninnocent ligand preparation electrochem; crystal structure molybdacarborane containing bipyridine phenanthroline noninnocent ligand; mol structure molybdacarborane containing bipyridine phenanthroline noninnocent ligand; Raman spectroscopy; carborane; density functional theory calculations; molybdacarborane; spectroelectrochemistry.
The molybdacarboranes [3-{L-κ2N,N}-3-(CO)2-closo-3,1,2-MoC2B9H11] (L = 2,2′-bipyridine (2,2′-bpy, 1a) or 1,10-phenanthroline (1,10-phen, 1b)) incorporating known potentially noninnocent ligands (CO, 2,2′-bpy, 1,10-phen) and the nonspectator nido-carborane ([η5-C2B9H11]2-) ligand were prepared and fully characterized. High-resolution mass spectrometry, single-crystal x-ray diffraction methods, spectroscopy (IR, (resonance) Raman, NMR), cyclic voltammetry and spectroelectrochem. (electrochem. properties) were supported by theor. studies of the electronic structure (DFT, CAS-SCF, TD-DFT).
Chemistry – A European Journal published new progress about Carboranes Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), SPN (Synthetic Preparation), PROC (Process), PREP (Preparation) (molybdacarboranes containing N,N-donor ligands). 366-18-7 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2, Formula: C10H8N2.