Shirra, Alexander; Suckling, Colin J. published an article in 1977, the title of the article was Pyridinium salts and dihydropyridines; mechanistic studies of the redox reaction between pyridinium salts and alkoxides in tetrahydrofuran.SDS of cas: 636-73-7 And the article contains the following content:
A model system for NAD-dependent redox reactions was designed to assess the involvement of covalent adducts as intermediates. The system consisted of 3-substituted 1-n-heptylpyridinium salts and substituted benzyl alkoxides. Although covalent adducts were found in the reaction mixture, studies of substituent effects and other structural variations did not show that A covalent intermediate is on the reaction path. The experimental process involved the reaction of Pyridine-3-sulfonic acid(cas: 636-73-7).SDS of cas: 636-73-7
The Article related to redox pyridinium alkoxide mechanism, nad redox model system, Physical Organic Chemistry: Oxidation-Reduction Reactions (Including Hydrogenation) and other aspects.SDS of cas: 636-73-7