Safety of 2,5-DibromopyridineIn 2022 ,《Controlling the Complexity and Interconversion Mechanisms in Self-Assembled [Fe2L3]4+ Helicates and [Fe4L6]8+ Cages》 was published in Angewandte Chemie, International Edition. The article was written by Siddique, Rashid G.; Arachchige, Kasun S. A.; Al-Fayaad, Hydar A.; Thoburn, John D.; McMurtrie, John C.; Clegg, Jack K.. The article contains the following contents:
Self-assembled coordination cages and metal-organic frameworks have relied extensively on sym. ligands in their formation. Here the authors prepared a relatively simple system employing an unsym. ligand that results in two distinct self-assembled structures, a [Fe2L3]4+ helicate and a [Fe4L6]8+ cage composed of 10 interconverting diastereomers and their enantiomers. The steric profile of the ligand controls the complexity, thermodn. and kinetics of interconversion of the system. In the experiment, the researchers used 2,5-Dibromopyridine(cas: 624-28-2Safety of 2,5-Dibromopyridine)
2,5-Dibromopyridine(cas: 624-28-2) belongs to pyridine. Pyridine and pyridine-derived structures are privileged pharmacophores in medicinal chemistry and an essential functionality for organic chemists. As the prototypical π-deficient heterocycle, pyridine illustrates distinctive chemistry as both substrate and reagent. Safety of 2,5-Dibromopyridine