Simler, Thomas’s team published research in Organometallics in 35 | CAS: 338800-13-8

Organometallics published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C5H5N3S, Category: pyridine-derivatives.

Simler, Thomas published the artcileChromium(II) Pincer Complexes with Dearomatized PNP and PNC Ligands: A Comparative Study of Their Catalytic Ethylene Oligomerization Activity, Category: pyridine-derivatives, the publication is Organometallics (2016), 35(24), 4044-4049, database is CAplus.

Monodeprotonation of the 2,6-bis(di-tert-butylphosphinomethyl)pyridine (tBuPNtBuP) at the α-lutidinyl-CH2 position with 1 equiv of KCH2C6H5 and concomitant dearomatization of the heterocycle afforded K(tBuP*NatBuP) (tBuP* = di-tert-Bu vinylic P donor, tBuP = PtBu2, Na = anionic amido N donor); its transmetalation with [CrCl2(THF)2] afforded the Cr(II) complex [Cr(tBuP*NatBuP)Cl] (A). The x-ray diffraction anal. of A established a slightly distorted square-planar coordination geometry at the metal center and confirmed retention of the dearomatized coordinated ligand. The catalytic activity of A in ethylene oligomerization was studied and compared with that of the related Cr(II) complexes [Cr(tBuP*NaCNHC)Cl] (B) and [Cr{Cr(tBuP*NatBuP*)Cl}2] (C) previously reported.

Organometallics published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C5H5N3S, Category: pyridine-derivatives.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem