Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 122918-25-6, Name is 6-Bromopicolinonitrile, SMILES is N#CC1=NC(Br)=CC=C1, in an article , author is Ulrich, Sebastian, once mentioned of 122918-25-6, COA of Formula: C6H3BrN2.
Basicity Enhancement by Multiple Intramolecular Hydrogen Bonding in Organic Superbase N,N ‘,N ”,N ”’-Tetrakis(3-(dimethylamino)propyl)triaminophosphazene
With the synthesis of N,N’,N ”,N”’-tetrakis(3-(dimethylamino)propyl)triaminophosphazene (TDMPP, 1), we present the first phosphazene superbase with enhanced basicity through the effect of multiple intramolecular hydrogen bonding (IHB). Due to intramolecular solvation of four NH protons, the proton affinity is even higher than that of second-order phosphazene (dma)P-2-tBu. X-ray structural proof, NMR titration experiments, and computational investigations provide a more detailed quantitative description of the IHB influence on the superbasicity of 1 in solid-state, solution, and the gas-phase.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem