Sindhuja, Elangovan published the artcilePalladium(II) thiocarboxamide complexes: synthesis, characterisation and application to catalytic Suzuki coupling reactions, Product Details of C13H13N, the publication is Dalton Transactions (2012), 41(17), 5351-5361, database is CAplus and MEDLINE.
A simple route to synthesize palladium(II) complexes from the reaction of N-substituted pyridine-2-thiocarboxamide ligands and PdCl2(PPh3)2 has been developed. The new complexes are very soluble in common solvents and have been fully characterized (elemental anal., FTIR, 1H, 31P, 13C-NMR), including an x-ray diffraction anal. The mol. structures of all the complexes were determined and reveal square planar geometry around Pd with little distortion. The complexes were tested in the Suzuki coupling of electronically deactivated aryl and heteroaryl bromides and have much greater activity, without using any promoting additives or phase transfer agent under aerobic conditions. Higher reaction rates were obtained by varying R substituents on the aromatic ring of pyridine-2-thiocarboxamide. The effect of other variables on the cross-coupling reaction, such as temperature, solvent and base, is also reported.
Dalton Transactions published new progress about 85237-71-4. 85237-71-4 belongs to pyridine-derivatives, auxiliary class Pyridine,Benzene, name is 5-Methyl-2-(p-tolyl)pyridine, and the molecular formula is C17H20ClN3, Product Details of C13H13N.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem