Safety of 2-(2-Hydroxyethyl)pyridineIn 2018 ,《Preparation of the Ru3(CO)8-pyridine-alcohol cluster and its use for the selective catalytic transformation of primary to secondary amines》 appeared in Dalton Transactions. The author of the article were Singh, Ajeet; Mobin, Shaikh M.; Mathur, Pradeep. The article conveys some information:
The synthesis of pyridine alc. based ruthenium carbonyl clusters Ru3(hep)2(CO)8 , Ru3(hpp)2(CO)8 , and Ru3(bhmp-H)2(CO)8 {hep-H = 2-(2-hydroxyethyl)pyridine, hpp-H = 2-(3-hydroxypropyl)pyridine and bhmp-H2 = 2,6-bis(hydroxymethyl)pyridine} was carried out by the reaction of the corresponding pyridine-alc. ligands with Ru3(CO)12. Clusters Ru3(hep)2(CO)8 , Ru3(hpp)2(CO)8 , and Ru3(bhmp-H)2(CO)8 were characterized using elemental anal., NMR, FTIR, mass spectrometry and single-crystal x-ray structures. The clusters were explored for the selective catalytic transformation of primary amines into secondary amines using alcs. as the mono-alkylating agents via hydrogen transfer reactions. All three display efficient catalytic activity with 1 being the most effective.2-(2-Hydroxyethyl)pyridine(cas: 103-74-2Safety of 2-(2-Hydroxyethyl)pyridine) was used in this study.
2-(2-Hydroxyethyl)pyridine(cas: 103-74-2) belongs to pyridine. The basicity and metallophilic high donor number of these π-deficient systems has long favored them as ligands in metal catalysis. The last decade saw pyridine assume a stronger role as functional group for directed C–H oxidation/activation.Safety of 2-(2-Hydroxyethyl)pyridine