Smith, Ashleigh D.’s team published research in Polyhedron in 114 | CAS: 338800-13-8

Polyhedron published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C5H10O, Related Products of pyridine-derivatives.

Smith, Ashleigh D. published the artcileSynthesis, characterization and reactivity of iron- and cobalt-pincer complexes, Related Products of pyridine-derivatives, the publication is Polyhedron (2016), 286-291, database is CAplus.

The tBuPONOP (2,6-bis(di-tert-butylphosphinito)pyridine) complexes of iron and cobalt, (tBuPONOP)FeCl2 (1) and (tBuPONOP)CoCl2 (2), were prepared Both complexes are paramagnetic and the solid-state structures of 1 and 2 were determined by single crystal x-ray diffraction studies. Analogous Fe and Co complexes of the tBuPNP (2,6-bis(di-tert-butyl-phosphinomethyl)pyridine) ligand (3 and 4, resp.) were prepared to allow comparison between the closely related pincer ligands in the hydrosilylation of carbonyl moieties. All four complexes are catalytically active when treated with NaBEt3H, which was assumed to generate a metal-hydride species in-situ.

Polyhedron published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C5H10O, Related Products of pyridine-derivatives.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem