Micelle-enabled clean and selective sulfonylation of polyfluoroarenes in water under mild conditions was written by Smith, Justin D.;Ansari, Tharique N.;Andersson, Martin P.;Yadagiri, Dongari;Ibrahim, Faisal;Liang, Shengzong;Hammond, Gerald B.;Gallou, Fabrice;Handa, Sachin. And the article was included in Green Chemistry in 2018.HPLC of Formula: 700-16-3 The following contents are mentioned in the article:
Proline-based designer surfactant FI-750-M has been demonstrated to enable selective nucleophilic aromatic substitution of polyfluoro(hetero)arenes RF (R = 2,3,5,6-tetrafluoro-4-cyanophenyl, 3-chloro-2,5,6-trifluoropyridin-4-yl, 2,3,5,6-tetrafluoro-4-formylphenyl, etc.) by sulfinate salts R1S(O)2X (R1 = 4-CH3C6H4, tetrahydrofuran-3-yl, 1-[(tert-butoxy)(oxo)methane]azetidin-3-yl, etc.; X = Na, Li) in water under mild micellar conditions. Resultant sulfones RS(O)2R1 were obtained from diverse substrates in good yields without side product formation and could usually be purified by simple filtration. The nature of micelles of FI-750-M and the solubility of coupling partners in different micellar regions has been supported by dynamic light scattering, cryo-TEM, and DFT calculations This study involved multiple reactions and reactants, such as 2,3,4,5,6-Perfluoropyridine (cas: 700-16-3HPLC of Formula: 700-16-3).
2,3,4,5,6-Perfluoropyridine (cas: 700-16-3) belongs to pyridine derivatives. Pyridine has a dipole moment and a weaker resonant stabilization than benzene (resonance energy 117 kJ路mol鈭? in pyridine vs. 150 kJ路mol鈭? in benzene). Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. HPLC of Formula: 700-16-3