Chemistry, like all the natural sciences, SDS of cas: 103577-40-8, begins with the direct observation of nature¡ª in this case, of matter.103577-40-8, Name is 2-(((3-Methyl-4-(2,2,2-trifluoroethoxy)pyridin-2-yl)methyl)thio)-1H-benzo[d]imidazole, SMILES is FC(F)(F)COC1=C(C)C(CSC2=NC3=CC=CC=C3N2)=NC=C1, belongs to pyridine-derivatives compound. In a document, author is Zhao, Fu-Jie, introduce the new discover.
Ditopic Chiral Pineno-Fused 2,2 ‘:6 ‘,2 ”-Terpyridine: Synthesis, Self-Assembly, and Optical Properties
The syntheses of 4′-substituted chiral 2,2′:6′,2 ”-terpyridine (tpy) ligands with predetermined configurations and directionalities are rather limited in the supramolecular chemistry field. In this study, a carbazole-linked ditopic chiral ligand L was synthesized using 4’-bromo-substituted pineno-fused tpy 5 as the precursor. Upon complexation with Cd(NO3)(2)center dot 4H(2)O and Zn-(NO3)(2)center dot 6H(2)O, two enantiomerically pure metallosupra-molecules, [Cd3L3] and [Zn4L4], have been self-assembled and characterized by NMR, electrospray ionization-mass spectrometry, traveling wave ion mobility-mass spectrometry, and DOSY analysis. In addition, their optical properties are characterized by UV-vis, fluorescence, circular dichroism, and circularly polarized luminescence, suggesting an efficiency transmission and amplification of chirality from the ligand to metal center via self-assembly.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 103577-40-8. SDS of cas: 103577-40-8.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem