Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Organic Letters called Phosphorylation Organocatalysts Highly Active by Design, Author is Fallek, Amit; Weiss-Shtofman, Mor; Kramer, Maria; Dobrovetsky, Roman; Portnoy, Moshe, which mentions a compound: 50816-19-8, SMILESS is OCCCCCCCCBr, Molecular C8H17BrO, Recommanded Product: 50816-19-8.
The activity of nucleophilic organocatalysts for alc./phenol phosphorylation was enhanced through attaching oligoether appendages to a benzyl substituent on imidazole- or aminopyridine-based active units, presumably because of stabilizing n-cation interactions of the ethereal oxygens with the pos. charged aza-heterocycle in the catalytic intermediates, and was substantially higher than that of known benchmark catalysts for a range of substrates. D. functional theory calculations and the study of analogs having a lower potential for such stabilizing interactions support our hypothesis.
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