Recently I am researching about HETEROPOLYTUNGSTATE DERIVATIVES; HETEROGENEOUS CATALYSTS; CYCLOHEXANE OXIDATION; W-183 NMR; METAL; KEGGIN; PERFORMANCE; FUNCTIONALIZATION; HYDROCARBONS; OXYGENATION, Saw an article supported by the Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21571050, 21573056, 21771053, 21771054]; 2019 Student Innovative Pilot Plan of Henan University [201910475079]. Formula: C12H9NO. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Ma, XY; Wang, P; Liu, ZH; Xin, CH; Wang, SY; Jia, JG; Ma, PT; Niu, JY; Wang, JP. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone
POM-supported metal carbonyl derivatives (PMCDs) represent a family of tremendous potential catalysts owing to their peculiar physical and chemical properties. Yet low-valence transition metal-substituted Dawson-type PMCD catalysts are uncommon. Hence, we synthesized a tricobalt-substituted PMCDs by conventional aqueous solution method, [Na(H2O)(5)](NH4)(7)[P2W15O56Co3(H2O)(3)(OH)(3)Re(CO)(3)]center dot 13H(2)O (1), and characterized by single crystal X-ray diffraction crystallography, IR, and thermogravimetric analyses (TGA), etc. The obtained compound 1 was employed as a catalyst for the oxidation of diphenylmethane (DPM) to benzophenone, giving 96.8% yield in the presence of tert-butyl hydroperoxide (TBHP) and pyridine. The control experiments indicate that Co metal ion plays an important role in the catalytic reactions. As a side note, the electrospray ionization mass spectrometry (ESI-MS) and UV spectroscopy showed that 1 can retain its integrity in solution, and magnetic measurements indicated that 1 exhibited a weaker ferromagnetic interaction at low temperature.
Formula: C12H9NO. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Ma, XY; Wang, P; Liu, ZH; Xin, CH; Wang, SY; Jia, JG; Ma, PT; Niu, JY; Wang, JP or concate me.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem