Application In Synthesis of 2-(Bromomethyl)pyridine hydrobromideIn 2019 ,《Synthesis of Iridium(III) and Rhodium(III) Complexes Bearing C8-Metalated Theophylline Ligands by Directed C-H Activation》 was published in Organometallics. The article was written by Tan, Tristan Tsai Yuan; Hahn, F. Ekkehardt. The article contains the following contents:
The directed C-H activation at the C8 position of N-donor tethered theophylline with iridium(III) and rhodium(III) is presented. The donor strength of the N-tethered donor group has been varied. Proligands bearing a strongly donating imidazolin-2-ylidene or the weaker donating pyridine group were both metalated under similar conditions, suggesting that the electron d. at the metal center does not play a significant role in the C-H activation step, which was concluded to proceed via a carboxylate-assisted route. The synthesis and characterization of iridium(III) and rhodium(III) complexes bearing chelating CNHC^Cazolato ligands (M = Ir: [4], M = Rh: [5]) and Npyridine^Cazolato ligands (M = Ir: [7], M = Rh: [8]) are reported. In addition, the NHC complexes which are the precursors to the CNHC^Cazolato complexes (M = Ir: [2], M = Rh: [3]) were isolated and characterized. In the part of experimental materials, we found many familiar compounds, such as 2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8Application In Synthesis of 2-(Bromomethyl)pyridine hydrobromide)
2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8) belongs to pyridine. Pyridines, quinolines, and isoquinolines have found a function in almost all aspects of organic chemistry. Pyridine has found use as a solvent, base, ligand, functional group, and molecular scaffold. As structural elements, these moieties are potent electron-deficient groups, metal-directing functionalities, fluorophores, and medicinally important pharmacophores. Application In Synthesis of 2-(Bromomethyl)pyridine hydrobromide