On August 4, 2021, Tanaka, Jin; Nagashima, Yuki; Araujo Dias, Antonio Junio; Tanaka, Ken published an article.Formula: C17H20BNO2 The title of the article was Photo-Induced ortho-C-H Borylation of Arenes through In Situ Generation of Rhodium(II) Ate Complexes. And the article contained the following:
Photoinduced in situ “oxidation” of half-sandwich metal complexes to “high-valent” cationic metal complexes has been used to accelerate catalytic reactions. Here, we report the unprecedented photoinduced in situ “reduction” of half-sandwich metal [Rh(III)] complexes to “low-valent” anionic metal [Rh(II)] ate complexes, which facilitate ligand exchange with electron-deficient elements (diboron). This strategy was realized by using a functionalized cyclopentadienyl (CpA3) Rh(III) catalyst we developed, which enabled the basic group-directed room temperature ortho-C-H borylation of arenes. The experimental process involved the reaction of 2-(2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)pyridine(cas: 1349171-28-3).Formula: C17H20BNO2
The Article related to photocatalyzed regioselective borylation arene rhodium ate in situ catalyst, mol structure optimized rhodium complex transition state potential energy, half sandwich rhodium ate complex in situ catalyst borylation and other aspects.Formula: C17H20BNO2