Tanaka, Katsumasa; Hattori, Hiroshi; Yabe, Ryota; Nishimura, Takahiro published an article in 2022, the title of the article was Ir-Catalyzed cyclization of α,ω-dienes with an N-methyl group via two C-H activation steps.Related Products of 156267-13-9 And the article contains the following content:
Iridium-catalyzed sp3 C-H alkylation of an N-Me group with 1,5- and 1,6-dienes proceeded to give five- and six-membered carbocyclic compounds, resp., in high yields. The reaction involved intermol. alkylation of the N-Me group with a vinyl moiety and subsequent intramol. cyclization at the β-position of the initially formed alkylated intermediate. The reaction using a chiral bidentate phosphine ligand enabled the asym. synthesis of the cyclic compounds The experimental process involved the reaction of N,3-Dimethylpyridin-2-amine(cas: 156267-13-9).Related Products of 156267-13-9
The Article related to methylpyridinamine diene iridium catalyst regioselective bond activation alkylation cyclization, cycloalkylmethylpyridinamine enantioselective preparation, Heterocyclic Compounds (One Hetero Atom): Pyridines and other aspects.Related Products of 156267-13-9