Taya, Toshiki published the artcileKinetic study of solvent extraction of nickel(II) from aqueous solution by some heterocyclic substituted-hydrazones, Application In Synthesis of 2215-33-0, the publication is Analytical Sciences (1991), 7(Suppl.), 21-4, database is CAplus.
Solvent extraction of nickel(II) complexes with five heterocyclic hydrazones (containing pyridine- or/ and quinoline-nitrogen atoms as the coordinating sites) into chloroform or benzene was studied kinetically at 25°C and μ = 0.1 by means of a spectrophotometric method. The kinetics of extraction of nickel(II) ion is first order in each of the aqueous nickel(II) concentration and the hydrazone concentration in the organic phase. The observed second-order rate constant, kobs, -pH profiles suggest three rate-determining steps to be considered in the aqueous phase: Ni2+ + H2L+ â? Ni2+ + HL â?and Ni(OH)+ + HL â? The rate constant for the formation of 1:1 complexes with 2-pyridylmethanone 2-pyridylhydrazone (PAPH) was consistent with those for bipyridine and terpyridine. Replacement of pyridyl group by quinolyl group affects the distribution constant (Kd) of the ligand between the two phases rather than the rate constants The influence of the structure of ligands on the rate constants is also discussed.
Analytical Sciences published new progress about 2215-33-0. 2215-33-0 belongs to pyridine-derivatives, auxiliary class Pyridine,Amine, name is 2-((2-(Pyridin-2-yl)hydrazono)methyl)pyridine, and the molecular formula is C18H34N4O5S, Application In Synthesis of 2215-33-0.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem