Safety of Bis(pyridin-2-ylmethyl)amineIn 2019 ,《Synthetic Polymers To Promote Cooperative Cu Activity for O2 Activation: Poly vs. Mono》 was published in Journal of the American Chemical Society. The article was written by Thanneeru, Srinivas; Milazzo, Nicholas; Lopes, Aaron; Wei, Zichao; Angeles-Boza, Alfredo M.; He, Jie. The article contains the following contents:
The authors report polymer-promoted cooperative catalysis of Cu for O activation. Random copolymers containing dipicolylamine as binding motifs are designed to coordinate type-3 Cu sites. The Cu-copolymers show a 6-8-fold activity enhancement, compared to the mol. complex of Cu with an identical coordination site. Michaelis-Menten anal. demonstrates that the kinetic enhancement results from flexible polymer-promoted cooperative catalysis among multi-Cu sites despite the imposed thermodn. barrier. These observations provide guidance for the bioinspired design of metallopolymers as soluble catalysts with high activity. In the experiment, the researchers used many compounds, for example, Bis(pyridin-2-ylmethyl)amine(cas: 1539-42-0Safety of Bis(pyridin-2-ylmethyl)amine)
Bis(pyridin-2-ylmethyl)amine(cas: 1539-42-0) is a secondary amine with two picolyl substituents. The compound is a tridentate ligand in coordination chemistry and commonly used to produce Zn-based chemosensors/probes, such as Zinpry.Safety of Bis(pyridin-2-ylmethyl)amine