Tomas, Federico M. A.; Peyrot, Analia M.; Fagalde, Florencia published their research in Polyhedron in 2021. The article was titled 《Synthesis, spectroscopic characterization and theoretical studies of polypyridine homoleptic Cu (I) complexes》.Computed Properties of C12H12N2 The article contains the following contents:
The authors focus on the synthesis and physicochem. characterization of four mononuclear copper(I) complexes with π-conjugated ligands substituted by Me groups of formulas [CuL2]+ with L = dmb, dmp, tmp and phen (dmb = 4,4′-dimethyl-2,2′-bipyridine; dmp = 5,6-dimethyl-1,10- phenanthroline; tmp = 3,4,7,8-tetramethyl-1,10-phenanthroline and phen = 1,10-phenanthroline). By TD-DFT it was possible to discuss and rationalize the geometry of the complexes and the origin of metal-to-ligand charge transfer in a square-planar distortion state. In the part of experimental materials, we found many familiar compounds, such as 4,4′-Dimethyl-2,2′-bipyridine(cas: 1134-35-6Computed Properties of C12H12N2)
4,4′-Dimethyl-2,2′-bipyridine(cas: 1134-35-6) is used as a chemical Intermediate. It can be used for the determination of ferrous and cyanide compounds.Computed Properties of C12H12N2 Furthermore, 4,4′-Dimethyl-2,2′-bipyridine is used in the synthesis of a series of o-phenanthroline-substituted ruthenium(II) complexes.