Reference of 2-(Bromomethyl)pyridine hydrobromideIn 2019 ,《Iron(II) tetrafluoroborate complexes of new tetradentate C-scorpionates as catalysts for the oxidative cleavage of trans-stilbene with H2O2》 appeared in Dalton Transactions. The author of the article were Wang, Denan; Gardinier, James R.; Lindeman, Sergey V.. The article conveys some information:
Attachment of a 2-methylpyridyl group onto the unique 1-nitrogen atom on nitrogen-confused C-scorpionates with either pyrazol-1-yl or 3,5 dimethylpyrazol-1-yl donors gives two new cis-directing tetradentate-N4 ligands (L and L*). The complexes [(L or L*)Fe(CH3CN)2](BF4)2 (1 or 2) were prepared, fully characterized, and investigated for their ability to catalyze the oxidative cleavage of trans-stilbene in CH3CN. Complexes 1 and 2 are capable of catalyzing stilbene cleavage when H2O2 is used as an oxidant but up to six different products are formed, with C:C cleavage products (benzaldehyde and benzoic acid) dominating over four products of oxygen transfer. Catalytic amounts of 1 or 2 enhance the ability for the organic photocatalyst riboflavin tetraacetate to use atm. oxygen and blue light irradiation (450-460 nm) to selectively cleave stilbene to benzaldehyde. However, when benzaldehyde oxidizes further to benzoic acid, the iron species begin giving increasing amounts of stilbene oxygenation products.2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8Reference of 2-(Bromomethyl)pyridine hydrobromide) was used in this study.
2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8) belongs to pyridine. Pyridine and pyridine-derived structures are privileged pharmacophores in medicinal chemistry and an essential functionality for organic chemists. As the prototypical π-deficient heterocycle, pyridine illustrates distinctive chemistry as both substrate and reagent. Reference of 2-(Bromomethyl)pyridine hydrobromide