Iridium-catalyzed intermolecular directed dehydrogenative ortho C-H silylation was written by Wang, Hong;Wang, Guanghui;Li, Pengfei. And the article was included in Organic Chemistry Frontiers in 2017.Name: 2-Isopropylpyridine This article mentions the following:
An efficient method for iridium-catalyzed direct silylation of C(sp2)-H and C(sp3)-H bonds using HSiMe(OSiMe3)2 as the silylating reagent is described. The reaction is amenable to various directing groups under simple and mild conditions leading to the mono- and regioselective synthesis of versatile organosilane compounds In the experiment, the researchers used many compounds, for example, 2-Isopropylpyridine (cas: 644-98-4Name: 2-Isopropylpyridine).
2-Isopropylpyridine (cas: 644-98-4) belongs to pyridine derivatives. In contrast to benzene, Pyridine’s electron density is not evenly distributed over the ring, reflecting the negative inductive effect of the nitrogen atom. Pyridine derivatives are also useful as small-molecule α-helix mimetics that inhibit protein-protein interactions, as well as functionally selective GABA ligands.Name: 2-Isopropylpyridine