Wang, Shengdong; Huang, Haiyun; Roisnel, Thierry; Bruneau, Christian; Fischmeister, Cedric published the artcile< Base-Free Dehydrogenation of Aqueous and Neat Formic Acid with Iridium(III) Cp*(dipyridylamine) Catalysts>, Safety of 2-Bromo-N,N-dimethylpyridin-4-amine, the main research area is preparation crystal structure iridium cyclopentadiynyl dipyridylamine complex; cyclic voltammetry iridium cyclopentadiynyl dipyridylamine complex; Dehydrogenation formic acid iridium cyclopentadiynyl dipyridylamine complex catalyst; N ligands; dehydrogenation; energy conversion; hydrogen; iridium.
The selective dehydrogenation of formic acid by iridium(III) Cp*(dipyridylamine) catalysts is reported. The electron-enriched catalyst [IrIIICp*{(4-dimethylaminopyridin-2-yl-κN)(pyridin-2′-yl-κN)amine}(OSO3)] gave the best performances enabling the base free dehydrogenation of aqueous and neat formic acid. In both cases the reaction was selective with no carbon monoxide detectable. The IrIII complex demonstrated latent behavior, which may be of practical utility. Exptl. results suggest an outer-sphere interaction with the ligand.
ChemSusChem published new progress about Crystal structure. 396092-82-3 belongs to class pyridine-derivatives, and the molecular formula is C7H9BrN2, Safety of 2-Bromo-N,N-dimethylpyridin-4-amine.