The author of 《Nickel-Catalyzed 1,2-Arylboration of Vinylarenes》 were Wang, Wang; Ding, Chao; Pang, Hailiang; Yin, Guoyin. And the article was published in Organic Letters in 2019. Synthetic Route of C6H6BrN The author mentioned the following in the article:
A novel Ni-catalyzed 1,2-arylboration of vinylarenes is reported. A variety of 2-boryl-1,1-diarylalkanes, which constitute a class of significant pharmacophores, are efficiently prepared from readily available olefins and aryl halides in the presence of bis(pinacolato)diboron under mild reaction conditions. The success of this three-component cascade is mainly attributed to the redox-active N-based ligand. Also, this method exhibits good functional group tolerance and excellent chemo- and stereoselectivity. In the part of experimental materials, we found many familiar compounds, such as 2-Bromo-5-methylpyridine(cas: 3510-66-5Synthetic Route of C6H6BrN)
2-Bromo-5-methylpyridine(cas: 3510-66-5) belongs to pyridine. When pyridine is adsorbed on oxide surfaces or in porous materials, the following species are commonly observed: (i) pyridine coordinated to Lewis acid sites, (ii) pyridine H-bonded to weakly acidic hydroxyls, and (iii) protonated pyridine. At high coverage, physisorbed pyridine and protonated dimers can also be observed.Synthetic Route of C6H6BrN