Warr, Rebecca J. published the artcileInorganic asymmetric synthesis: asymmetric synthesis of a two-bladed propeller, octahedral metal complex, Related Products of pyridine-derivatives, the publication is Inorganic Chemistry (2006), 45(21), 8618-8627, database is CAplus and MEDLINE.
A C2 hexadentate, in which two pyridine-2-aldehyde 2′-pyridylhydrazone (PAPHY) groups are linked to a chiral auxiliary derived from (R,R)-tartaric acid, (R,R)-I, reacts with Fe(II) benzenesulfonate to give the two-bladed propeller, octahedral complex (PFe)-[Fe{(R,R)-I}](PhSO3)2 with complete diastereoselectivity, as determined by 1H NMR spectroscopy and x-ray crystallog. Saponification of the ester linkages and deprotonation of the hydrazone-NH groups in the configurationally pure diastereomer affords (PFe)-[Fe(5-HOCH2PAPY)2] with 85% retention of configuration at the Fe stereocenter, as determined by reprotonation of the neutral complex with enantiomerically pure (aR)-binaphthyl H3PO4 and anal. of the 1H NMR spectrum of the mixture of diastereomeric salts produced. This is the 1st asym. synthesis of a two-bladed propeller, octahedral metal complex by the classical organic methodol. of chiral auxiliary-directed, asym. synthesis.
Inorganic Chemistry published new progress about 2215-33-0. 2215-33-0 belongs to pyridine-derivatives, auxiliary class Pyridine,Amine, name is 2-((2-(Pyridin-2-yl)hydrazono)methyl)pyridine, and the molecular formula is C5H5BO4S, Related Products of pyridine-derivatives.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem